I know little or nothing about the cleaning services of New York's Madame Paulette, but the company's Professional Stain Removal Kit is unsurpassed in my experience. The point of on the spot stain removal is that the sooner a stain is removed the less it is likely to cause irreversible damage, and one of Madame Paulette's kits demonstrated this just the other day when it removed a salad dressing spot from the lapel of a jacket.
There are three primary stain groups that attack tailored clothing, those being earth, protein and oil based, and there is a formula designed to remove each of them in each kit. Just tear open the proper envelope, apply the wipe with its embedded formula to the stain, and then treat with the supplied rinse wipe. All the contents are biodegradable and rinse out with water.
Men who value their clothing are likely find the kit a great bargain at $12.50 per, or $50 for five.